Synthesis of (−) cephalosporolide E and (+) cephalosporolide F utilizing the vinylogous Mukaiyama type reaction with an α-chloro sulfide-Reference-Cited by-同舟云学术

Synthesis of (−) cephalosporolide E and (+) cephalosporolide F utilizing the vinylogous Mukaiyama type reaction with an α-chloro sulfide

Published:2016 Issue:77 Volume:6 Page:72877-72884
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Raghavan Sadagopan¹²³⁴⁵,Patel Javed Sardar¹²³⁴⁵,Ramakrishna K. V. S.⁶²³⁴

Affiliation:

1. Academy of Scientific and Innovative Research

2. Indian Institute of Chemical Technology

3. Hyderabad

4. India

5. Natural Products Chemistry Division

6. Centre for NMR and Structural Chemistry

Abstract

An asymmetric synthesis of (−)-cephalosporolide E and (+)-cephalosporolide F employing vinylogous Mukaiyama type reaction with an α-chloro sulfide, Noyori transfer hydrogenation and oxidative cyclization as the key steps is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA13861F

Reference31 articles.

1. Structures of the cephalosporolides B–F, a group of C10lactones from Cephalosporium aphidicola

2. 10-Membered Macrolides from the Insect Pathogenic Fungus Cordyceps militaris BCC 2816

3. Ascospiroketals A and B, Unprecedented Cycloethers from the Marine-Derived Fungus Ascochyta salicorniae

4. Penisporolides A and B, Two New Spiral Lactones from the Marine-derived Fungus Penicillium sp.

5. Cephalosporolides H and I, two novel lactones from a marine-derived fungus, penicillium sp.

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