Restriction of the rotational relaxation of a butadiyne-bridged porphyrin dimer in ultrathin films

Author:

Shokurov Alexander V.123ORCID,Meshkov Ivan N.123ORCID,Bulach Véronique45678,Gorbunova Yulia G.123910ORCID,Hosseini Mir Wais45678ORCID,Tsivadze Aslan Yu.123910,Arslanov Vladimir V.123,Selektor Sofia L.123ORCID

Affiliation:

1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

2. Moscow

3. Russia

4. Molecular Tectonics Laboratory

5. UMR UDS-CNRS

6. 7140 & icFRC

7. Université de Strasbourg

8. Strasbourg

9. Kurnakov Institute of General and Inorganic Chemistry

10. Russian Academy of Sciences

Abstract

A way to stabilize the less energetically viable orthogonal conformation of a porphyrin dimer by means of a forced orientation at an interface is shown.

Funder

LabEx Chimie des Systèmes Complexes

Russian Science Foundation

Russian Foundation for Basic Research

Université de Strasbourg

Centre National de la Recherche Scientifique

Centre International de Recherche aux Frontières de la Chimie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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