Origin of electrocatalytic nitrogen reduction activity over transition metal disulfides: critical role of <i>in situ</i> generation of S vacancy-Reference-Cited by-同舟云学术

Origin of electrocatalytic nitrogen reduction activity over transition metal disulfides: critical role of in situ generation of S vacancy

Published:2024 Issue:14 Volume:12 Page:8438-8446
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Wang Tianyi¹,Guo Zhongyuan²^ORCID,Oka Hirofumi¹,Kumatani Akichika¹³⁴⁵^ORCID,Liu Chuangwei⁶,Li Hao¹^ORCID

Affiliation:

1. Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai, 980-8577, Japan

2. College of Environmental and Resource Sciences, Zhejiang University, Hangzhou, 310058, China

3. Institute of Engineering Innovation (IEI), School of Engineering, The University of Tokyo, Tokyo, 113-8656, Japan

4. Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Saitama 332-0012, Japan

5. Graduate School of Environmental Studies, Center for Science and Innovation in Spintronics (CSIS), Tohoku University, Sendai, Miyagi 980-8579, Japan

6. Key Lab for Anisotropy and Texture of Materials, School of Materials Science and Engineering, Northeastern University, Shenyang, 110819, China

Abstract

We identified an interesting electrochemistry-driven “in situ” generation of S-vacancies of transition metal disulfides, which serves as an origin of promising electrochemical ammonia synthesis activity.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D4TA00307A

Reference67 articles.

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