Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window-Reference-Cited by-同舟云学术

Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window

Published:2021 Issue:31 Volume:57 Page:3793-3796
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tarrieu Robert¹²³⁴⁵,Delgado Irene Hernandez⁶⁷⁸⁹¹⁰,Zinna Francesco⁶⁷⁸⁹¹⁰^ORCID,Dorcet Vincent¹³⁴⁵¹¹,Colombel-Rouen Sophie¹²³⁴⁵,Crévisy Christophe¹²³⁴⁵^ORCID,Baslé Olivier¹²³⁴⁵^ORCID,Bosson Johann⁶⁷⁸⁹¹⁰^ORCID,Lacour Jérôme⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Univ Rennes

2. Ecole Nationale Supérieure de Chimie de Rennes

3. CNRS

4. ISCR - UMR 6226

5. Rennes F-35000

6. Department of Organic Chemistry

7. University of Geneva

8. Quai Ernest Ansermet

9. 30

10. Geneva 4 CH-1211

11. France

Abstract

A cationic Helicene-NHC hybrid is readily prepared and used for the construction of Rh^I, Au^I and Au^III complexes. Ligand controlled chiroptical properties in the far-red spectral window are observed.

Funder

Université de Genève

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Centre National de la Recherche Scientifique

Région Bretagne

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00898F

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