On the consequences of the stereochemical activity of the Bi(iii) 6s2 lone pair in cyclen-based complexes. The [Bi(DO3A)] case-Reference-Cited by-同舟云学术

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On the consequences of the stereochemical activity of the Bi(iii) 6s2 lone pair in cyclen-based complexes. The [Bi(DO3A)] case

Published:2018 Issue:39 Volume:47 Page:13830-13842
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pujales-Paradela Rosa¹²³⁴⁵^ORCID,Rodríguez-Rodríguez Aurora¹²³⁴⁵,Gayoso-Padula Antonella¹²³⁴⁵,Brandariz Isabel¹²³⁴⁵^ORCID,Valencia Laura⁶⁷⁸⁹⁵,Esteban-Gómez David¹²³⁴⁵^ORCID,Platas-Iglesias Carlos¹²³⁴⁵^ORCID

Affiliation:

1. Universidade da Coruña

2. Centro de Investigacións Científicas Avanzadas (CICA) and Departamento de Química

3. Facultade de Ciencias

4. A Coruña

5. Spain

6. Departamento de Química Inorgánica

7. Facultad de Ciencias

8. Universidade de Vigo

9. 36310 Pontevedra

Abstract

The spatial arrangement of donor atoms in Bi(iii) cyclen derivatives modulates the orientation and activity of the 6s² lone pair.

Funder

Ministerio de Economía y Competitividad

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02602E

Reference72 articles.

1. Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure

2. The Development of the α-Particle Emitting Radionuclides 212Bi and 213Bi, and Their Decay Chain Related Radionuclides, for Therapeutic Applications

3. Targeted α-therapy: past, present, future?

4. Matching chelators to radiometals for radiopharmaceuticals

5. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

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