Halogenation of A-frame μ-carbido complexes: synthesis of μ2-halocarbynes-Reference-Cited by-同舟云学术

Halogenation of A-frame μ-carbido complexes: synthesis of μ2-halocarbynes

Published:2019 Issue:12 Volume:55 Page:1734-1737
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Barnett Harrison J.¹²³⁴^ORCID,Hill Anthony F.¹²³⁴^ORCID

Affiliation:

1. Research School of Chemistry

2. Australian National University

3. Canberra

4. Australia

Abstract

The new A-frame μ₂-carbido complexes [Rh₂(μ₂-C)X₂(μ₂-dppm)₂] (X = Cl, Br; dppm = Ph₂PCH₂PPh₂) react with PhICl₂ or [pyH][Br₃] to provide rare examples of μ₂-halocarbyne complexes [Rh₂(μ-CX)(μ-X)X₄(μ-dppm)₂] (X = Cl, Br).

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC09692A

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