Cu(0)-RDRP of methacrylates in DMSO: importance of the initiator-Reference-Cited by-同舟云学术

Cu(0)-RDRP of methacrylates in DMSO: importance of the initiator

Published:2018 Issue:18 Volume:9 Page:2382-2388
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Jones Glen R.¹²³⁴^ORCID,Whitfield Richard¹²³⁴^ORCID,Anastasaki Athina¹²³⁴⁵,Risangud Nuttapol¹²³⁴,Simula Alexandre⁶⁷⁸⁹,Keddie Daniel J.¹⁰¹¹¹²¹³⁴^ORCID,Haddleton David M.¹²³⁴^ORCID

Affiliation:

1. University of Warwick

2. Department of Chemistry

3. Coventry

4. UK

5. Materials Research Laboratory

6. POLYMAT and Kimika Aplikatua Saila

7. University of the Basque Country UPV/EHU

8. Donostia/San Sebastián

9. Spain

10. University of Wolverhampton

11. School of Biology

12. Chemistry and Forensic Science

13. Wolverhampton

Abstract

The controlled radical polymerization of methacrylates via Cu(0)-mediated RDRP is challenging in comparison to acrylates with most reports illustrating higher dispersities, lower monomer conversions and poorer end group fidelity relative to the acrylic analogues.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2018/PY/C7PY01196B

Reference49 articles.

1. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C

2. Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization

3. SARA ATRP or SET-LRP. End of controversy?

4. Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. A Critical Assessment of the SARA ATRP and SET-LRP Mechanisms

5. Comproportionation versus Disproportionation in the Initiation Step of Cu(0)-Mediated Living Radical Polymerization

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