A preorganized dual H-bond donor promotes benzoic acid active in the polymerization of δ-valerolactone-Reference-Cited by-同舟云学术

A preorganized dual H-bond donor promotes benzoic acid active in the polymerization of δ-valerolactone

Published:2017 Issue:36 Volume:8 Page:5570-5579
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Sun Herui¹²³⁴⁵,Xu Songquan¹²³⁴⁵,Li Zhenjiang¹²³⁴⁵^ORCID,Xu Jiaxi¹²³⁴⁵,Liu Jingjing¹²³⁴⁵,Wang Xin¹²³⁴⁵,Wang Haixin¹²³⁴⁵,Dong He¹²³⁴⁵,Liu Yaya¹²³⁴⁵,Guo Kai¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering

2. College of Biotechnology and Pharmaceutical Engineering

3. Nanjing Tech University

4. Nanjing 211816

5. China

Abstract

An enzyme-mimetic model follows squalene hopene cyclase is success in catalysis of ROP of δ-valerolactone in solution at room temperature by a carboxylic “strong” acid.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C7PY01192J

Reference72 articles.

1. Activated Monomer Cationic Polymerization of Lactones and the Application to Well-Defined Block Copolymer Synthesis with Seven-Membered Cyclic Carbonate

2. Thiourea binding with carboxylic acid promoted cationic ring-opening polymerization

3. Tripodal hydrogen bond donor binding with sulfonic acid enables ring-opening polymerization

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