Co2(CO)8 and unsaturated epoxides as unexpected partners in generating functionalized siloxane oils and cross-linked materials

Author:

Jakoobi Martin12345ORCID,Vivien Anthony12345,Camp Clément12345ORCID,Thieuleux Chloé12345ORCID

Affiliation:

1. Laboratory of Catalysis, Polymerization, Processes and Materials

2. CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon

3. Université de Lyon, Institut de Chimie de Lyon

4. F-69616 Villeurbanne

5. France

Abstract

The unexpected formation of cross-linked silicon materials was observed via hydrosilylation of unsaturated epoxides with polymethylhydrosiloxane using Co2(CO)8 as a catalyst.

Funder

European Commission

National Centre for Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference35 articles.

1. A. Colas and J.Curtis , Silicone Biomater. Hist. Chem. , 2004 , pp. 80–86

2. B. Marciniec , H.Maciejewski , C.Pietraszuk and P.Pawluc , Hydrosilylation A Comprehensive Review on Recent Advances , 2009

3. Imarc Services Private Limited, Silicones Market , Global Industry Trends, Share, Size, Growth, Opportunity and Forecast 2017–2022 , 2017

4. Catalytic Systems for the Cross-Linking of Organosilicon Polymers

5. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

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