σ-Hole interactions in organometallic catalysts: the case of methyltrioxorhenium(<scp>vii</scp>)-Reference-Cited by-同舟云学术

σ-Hole interactions in organometallic catalysts: the case of methyltrioxorhenium(vii)

Published:2023 Issue:4 Volume:52 Page:1030-1035
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Calabrese Miriam¹^ORCID,Pizzi Andrea¹^ORCID,Daolio Andrea¹^ORCID,Frontera Antonio²^ORCID,Resnati Giuseppe¹^ORCID

Affiliation:

1. NFMLab, Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta”, Politecnico di Milano, via L. Mancinelli 7, I-20131 Milano, Italy

2. Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

Abstract

Experimental and computational results prove that methyltrioxorhenium(vii), an efficient and reliable catalyst, forms σ-hole interactions with typical co-catalysts opposite to both O–Re and C–Re bonds.

Funder

Ministero dell'Università e della Ricerca

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03819F

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