On the role of C4 and C5 products in electrochemical CO2 reduction via copper-based catalysts

Author:

Rihm Simon D.123ORCID,Kovalev Mikhail K.2ORCID,Lapkin Alexei A.12ORCID,Ager Joel W.456ORCID,Kraft Markus1278ORCID

Affiliation:

1. Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge CB3 0AS, UK

2. Cambridge Centre for Advanced Research and Education in Singapore, CARES Ltd., 1 Create Way, CREATE Tower #05-05, 138602, Singapore

3. Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore

4. Department of Materials Science and Engineering, University of California Berkeley, Berkeley, California 94720, USA

5. Berkeley Education Alliance for Research in Singapore (BEARS), Ltd., 1 CREATE Way, 138602, Singapore

6. Materials and Chemical Sciences Divisions, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

7. School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, 637459, Singapore

8. The Alan Turing Institute, London, UK

Abstract

We identify many larger organics as products of electrochemical CO2 reduction in high-current GDEs – most interestingly, C4 and C5 isomers. The analysis of selectivity trends allows for deduction of general hypotheses to build a detailed mechanism.

Funder

Engineering and Physical Sciences Research Council

Cambridge Trust

Alan Turing Institute

Alexander von Humboldt-Stiftung

National Research Foundation Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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