Direct construction of biaryl-bridged 8–11 membered N-heterocycles via gold(<scp>i</scp>)-catalyzed intramolecular [4 + 2] benzannulation of N-tethered diynyl benzaldehydes-Reference-Cited by-同舟云学术

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Direct construction of biaryl-bridged 8–11 membered N-heterocycles via gold(i)-catalyzed intramolecular [4 + 2] benzannulation of N-tethered diynyl benzaldehydes

Published:2023 Issue:13 Volume:10 Page:3280-3287
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Bao Qing¹,Chen Jichao¹,Liu Zhen¹,Rao Weidong¹^ORCID

Affiliation:

1. Jiangsu Co-Innovation Center for Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

Abstract

A method for the expeditious assembly of a diverse range of biaryl-bridged 8–11 membered N-heterocycles that relies on gold(i)-catalyzed intramolecular [4 + 2] benzannulation of N-tethered diynyl benzaldehydes is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00250K

Reference74 articles.

1. Catalytic asymmetric synthesis of medium-sized bridged biaryls

2. Construction of Medium-Sized Rings by Gold Catalysis

3. A happy medium: the synthesis of medicinally important medium-sized rings via ring expansion

4. Formation of medium-ring heterocycles by diene and enyne metathesis

5. Alkaloids from Boophane flava

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1. KOH-mediated synthesis of amides from azides and 1,3-dicarbonyl compounds;New Journal of Chemistry;2024

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