Monitoring fragmentation and oligomerization of a di-μ-methoxo bridged copper(ii) complex: structure, mass spectrometry, magnetism and DFT studies-Reference-Cited by-同舟云学术

Monitoring fragmentation and oligomerization of a di-μ-methoxo bridged copper(ii) complex: structure, mass spectrometry, magnetism and DFT studies

Published:2019 Issue:34 Volume:48 Page:13094-13100
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shi Xing-Xing¹²³⁴,Chen Qiu-Jie⁵⁶⁷⁸⁹,Chen Xue-Li¹²³⁴,Zhang Yuexing⁵⁶⁷⁸⁹^ORCID,Kurmoo Mohamedally¹⁰¹¹¹²¹³¹⁴,Zeng Ming-Hua¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical Sciences

2. Guangxi Normal University

3. Guilin

4. P. R. China

5. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials

6. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules

7. College of Chemistry and Chemical Engineering

8. Hubei University

9. Wuhan

10. Université de Strasbourg

11. Institut de Chimie de Strasbourg

12. CNRS-UMR7177

13. Strasbourg Cedex 67070

14. France

Abstract

The flat binuclear [Cu₂(L)₂Cl₂] (HL = (1-methyl-1H-benzo[d]imidazole-2-yl)methanol) was studied by mass spectrometry and DFT calculations. Particularly, it shows strong antiferromagnetism with g = 2.20, J = −465 cm⁻¹ and zj = −0.83 cm⁻¹.