Thermal decomposition of t-butyl(nitro)malononitrile; evidence for the generation of a t-butyl cation via facile carbon–carbon bond heterolysis
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1990/C3/C39900000324
Reference11 articles.
1. Facile heterolysis of a carbon-carbon bond. Arylazodicyanomethanides as the leaving group capable of generating tert-cumyl cation and the hydrogen-bond-insusceptible behavior of the leaving group anions
2. Constituent analysis of the interaction of solvents with the leaving group anions for SN1–E1 reactions. Thermodynamic evidence for the nature of the conjugate base of p-nitrophenylhydrazonomalononitrile
3. The energy of the transition states and the intermediate cation in the ionization of 2-norbornyl derivatives. Where is the nonclassical stabilization energy?
4. Nitrierung von Malonester
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1. Structural dependence of heterolytic bond dissociation energy of carbon–carbon σ bonds in hydrocarbons;Journal of Physical Organic Chemistry;1998-03
2. Ionic Dissociation of Carbon—Carbon σ Bonds in Hydrocarbons and the Formation of Authentic Hydrocarbon Salts;Advances in Physical Organic Chemistry;1995
3. Quantitative Analysis of Solvent Effects on the Rate of Heterolysis Reactions: Relative Importance of Cation and Anion Solvation;Bulletin of the Chemical Society of Japan;1994-03
4. Thermal rearrangements and reactions of 5-alkyl-1,2,3,4,5-pentakis(methoxycarbonyl)cyclopentadienes;The Journal of Organic Chemistry;1994-01
5. Studies of thermal rearrangements of methyl 3-alkyl-3-methyl-3H-pyrazole-5-carboxylates. Concerted, stepwise, and unclassified mechanisms;The Journal of Organic Chemistry;1994-01
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