Efficient metal-free strategies for polymerization of a sterically hindered ionic monomer through the application of hard confinement and high pressure

Author:

Maksym Paulina12345ORCID,Tarnacka Magdalena12345ORCID,Dzienia Andrzej52346ORCID,Wolnica Kamila12345ORCID,Dulski Mateusz52347ORCID,Erfurt Karol89104,Chrobok Anna89104ORCID,Zięba Andrzej111213144,Brzózka Agnieszka151617184ORCID,Sulka Grzegorz151617184ORCID,Bielas Rafał19169104ORCID,Kaminski Kamil12345,Paluch Marian12345

Affiliation:

1. Institute of Physics

2. University of Silesia

3. 41-500 Chorzow

4. Poland

5. Silesian Center of Education and Interdisciplinary Research

6. Institute of Chemistry

7. Institute of Materials Science

8. Department of Chemical Organic Technology and Petrochemistry

9. Silesian University of Technology

10. 44-100 Gliwice

11. Department of Organic Chemistry

12. School of Pharmacy with the Division of Laboratory Medicine in Sosnowiec

13. Medical University of Silesia in Katowice

14. 41-200 Sosnowiec

15. Department of Physical Chemistry and Electrochemistry

16. Faculty of Chemistry

17. Jagiellonian University

18. 30-387 Krakow

19. Department of Physical Chemistry and Technology of Polymers

Abstract

The effect of hard confinement and high pressure on the progress of free-radical and reversible addition-fragmentation chain transfer polymerizations of sterically hindered 1-octyl-3-vinylimidazolium bis(trifluoromethanesulfonyl)imide ([OVIM][NTf2]) has been investigated.

Funder

Narodowe Centrum Nauki

Fundacja na rzecz Nauki Polskiej

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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