Ligand influence versus electronic configuration of d-metal ion in determining the fate of NIR emission from LnIII ions: a case study with CuII, NiII and ZnII complexes-Reference-Cited by-同舟云学术

Ligand influence versus electronic configuration of d-metal ion in determining the fate of NIR emission from LnIII ions: a case study with CuII, NiII and ZnII complexes

Published:2021 Issue:5 Volume:45 Page:2696-2709
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Verma Abhineet¹²³⁴⁵^ORCID,Hossain S. K. Saddam⁶⁷⁸⁵^ORCID,Sunkari Sailaja S.¹⁹³⁴⁵^ORCID,Reibenspies Joseph¹⁰¹¹¹¹²,Saha Satyen¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Science

3. Banaras Hindu University

4. Varanasi

5. India

6. School of Chemistry

7. University of Hyderabad

8. Hyderabad

9. Mahila Maha Vidhyalaya

10. X-ray Diffraction Laboratory

11. Texas A&M University

12. USA

Abstract

Based on fifteen lanthanide complexes, where Cu, Ni and Zn ions with a Schiff-base ligand act as an antenna, it is demonstrated that electronic configuration of the d-block metal ion is very crucial for obtaining emission in NIR region.

Funder

Council of Scientific and Industrial Research, India

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ04020G

Reference58 articles.

1. Lanthanide Luminescence for Biomedical Analyses and Imaging

2. Novel antennae for the sensitization of near infrared luminescent lanthanide cations