Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt(<scp>ii</scp>) complexes with zero-field hidden single-molecule magnet behaviour: the important role of the distortion of the coordination sphere and intermolecular interactions in the slow relaxation-Reference-Cited by-同舟云学术

Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt(ii) complexes with zero-field hidden single-molecule magnet behaviour: the important role of the distortion of the coordination sphere and intermolecular interactions in the slow relaxation

Published:2022 Issue:12 Volume:9 Page:2810-2831
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Landart-Gereka Aritz¹^ORCID,Quesada-Moreno María Mar¹^ORCID,Díaz-Ortega Ismael F.²³,Nojiri Hiroyuki²,Ozerov Mykhaylo⁴^ORCID,Krzystek J.⁴,Palacios María A.¹^ORCID,Colacio Enrique¹^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain

2. Institute for Materials Research, Tohoku University, Katahira, Sendai, 980-8577, Japan

3. Departamento de Química y Física-CIESOL, Universidad de Almería, Ctra. Sacramento s/n, 04120, Almería, Spain

4. National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA

Abstract

A N6-tripodal ligand allows the preparation of a family of prismatic mononuclear cationic CoII complexes with SMM behavior. Their axial anisotropy, magnetic relaxation and hysteresis width are modulated by the anion effects on the crystal structure.

Funder

Ministerio de Ciencia e Innovación

Agencia de Innovación y Desarrollo de Andalucía

Universidad de Granada

National Science Foundation

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00275B