Concise syntheses of (−)-habiterpenol and (+)-2,3-<i>epi</i>-habiterpenol <i>via</i> redox radical cyclization of alkenylsilane-Reference-Cited by-同舟云学术

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Concise syntheses of (−)-habiterpenol and (+)-2,3-epi-habiterpenol via redox radical cyclization of alkenylsilane

Published:2023 Issue:30 Volume:21 Page:6129-6133
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Taguchi Haruki¹,Kawaguchi Mayuko¹,Nagamitsu Tohru¹,Ohtawa Masaki¹^ORCID

Affiliation:

1. Laboratory of Synthetic Natural Products Chemistry and Medicinal Research Laboratories, School of Pharmacy, Kitasato University, 5-9-1 Shirokane, Minato-ku, Tokyo 108-8641, Japan

Abstract

The concise synthesis of (−)-habiterpenol in 11 steps was enabled by MHAT-initiated redox radical cyclization of alkenylsilane.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01062G

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1. Checkpoints: Controls That Ensure the Order of Cell Cycle Events

2. p53, the Cellular Gatekeeper for Growth and Division

3. Cell cycle phenotype-based optimization of G2-abrogating peptides yields CBP501 with a unique mechanism of action at the G2 checkpoint

4. AZD7762, a novel checkpoint kinase inhibitor, drives checkpoint abrogation and potentiates DNA-targeted therapies

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