Synthesis of β-keto sulfones via a multicomponent reaction through sulfonylation and decarboxylation-Reference-Cited by-同舟云学术

Synthesis of β-keto sulfones via a multicomponent reaction through sulfonylation and decarboxylation

Published:2017 Issue:4 Volume:4 Page:617-621
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yu Jiyao¹²³⁴,Mao Runyu⁵⁶⁷⁸,Wang Qingyu⁵⁶⁷⁸,Wu Jie⁵⁶⁷⁸⁹

Affiliation:

1. School of Chemistry and Biochemistry

2. Georgia Institute of Technology

3. Atlanta

4. USA

5. Department of Chemistry

6. Fudan University

7. Shanghai 200433

8. China

9. State Key Laboratory of Organometallic Chemistry

Abstract

A copper(i)-catalyzed synthesis of β-keto sulfones through reaction of aryldiazonium tetrafluoroborates, 3-arylpropiolic acids, sulfur dioxide, and water is realized. This reaction proceeds through a tandem radical process involving sulfonylation and decarboxylation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00026J

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