Polymorphism and orientation control of copper-dicarboxylate metal–organic framework thin films through vapour- and liquid-phase growth

Author:

Rubio-Giménez Víctor1ORCID,Carraro Francesco2ORCID,Hofer Sebastian3,Fratschko Mario3,Stassin Timothée1ORCID,Rodríguez-Hermida Sabina1,Schrode Benedikt3ORCID,Barba Luisa4ORCID,Resel Roland3ORCID,Falcaro Paolo2ORCID,Ameloot Rob1ORCID

Affiliation:

1. Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

2. Institute of Physical and Theoretical Chemistry, Graz University of Technology, Stremayrgasse 9/Z2, 8010 Graz, Austria

3. Institute of Solid State Physics, Graz University of Technology, Petersgasse 16, 8010 Graz, Austria

4. Istituto di Cristallografia – Sincrotrone Elettra, Consiglio Nazionale delle Ricerche, Area Science Park, 34142 Basovizza, Italy

Abstract

Liquid- and vapour-phase conversion of aligned Cu(OH)2 nanobelts into crystalline coatings of Cu-BDC and Cu-CDC MOFs, leads to differences in the crystal phase, morphology and crystallographic orientation.

Funder

TU Graz, Internationale Beziehungen und Mobilitätsprogramme

European Research Council

Fonds Wetenschappelijk Onderzoek

CALIPSOplus

Austrian Science Fund

H2020 Future and Emerging Technologies

Elettra-Sincrotrone Trieste

KU Leuven

Publisher

Royal Society of Chemistry (RSC)

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Vapor‐phase synthesis of MOF films;Bulletin of the Korean Chemical Society;2024-06-18

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