Alkynyl functionalized Al/P-based frustrated Lewis pairs – aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-PCC(H)-tBu]-Reference-Cited by-同舟云学术

Alkynyl functionalized Al/P-based frustrated Lewis pairs – aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-PCC(H)-tBu]

Published:2015 Issue:28 Volume:44 Page:12670-12679
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Klöcker Hans¹²³,Roters Steffi¹²³,Hepp Alexander¹²³,Uhl Werner¹²³

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Universität Münster

2. D-48149 Münster

3. Germany

Abstract

Hydroalumination of dialkynylphosphines by H-Al[CH(SiMe₃)₂]₂afforded alkenyl–alkynyl phosphines which eliminate dialkylaluminium alkynides spontaneously to form phosphaallenes, aryl-PCC(H)-^tBu.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01607J

Reference61 articles.

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