Reaction of phosphinylated nitrosoalkenes with electron-rich heterocycles. Electrophilic aromatic substitution vs. cycloaddition
Author:
Affiliation:
1. Departamento de Química Orgánica I
2. Facultad de Farmacia
3. Centro de Investigaciones y Estudios Avanzados “Lucio Lascaray”
4. Universidad del País Vasco UPV/EHU
5. 01006 Vitoria
Abstract
An experimental and theoretical study describe the behavior of phosphinyl nitrosoalkenes with indole, pyrrole and 2,5-dimethylpyrrole. Both, an electrophilic aromatic substitution and a [4 + 2] cycloaddition mechanism, were evaluated.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C6OB02486F
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