Structure-induced catalytic activity of Co–Zn double-metal cyanide complexes for terpolymerization of propylene oxide, cyclohexene oxide and CO2-Reference-Cited by-同舟云学术

Structure-induced catalytic activity of Co–Zn double-metal cyanide complexes for terpolymerization of propylene oxide, cyclohexene oxide and CO2

Published:2015 Issue:24 Volume:5 Page:18196-18203
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Sebastian Joby¹²³⁴⁵,Darbha Srinivas¹²³⁴⁵

Affiliation:

1. Catalysis Division

2. CSIR-National Chemical Laboratory

3. Pune 411 008

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

Abstract

Co–Zn DMC having monoclinic/rhombohedral structure were superior to the cubic complex for terpolymerization of propylene oxide, cyclohexene oxide and CO₂.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA00299K

Reference28 articles.

1. Catalysts for CO2/epoxide copolymerisation

2. Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

3. Physical properties of aliphatic polycarbonates made from CO2 and epoxides

4. Asymmetric Alternating Copolymerization and Terpolymerization of Epoxides with Carbon Dioxide at Mild Conditions

5. Alternating copolymerization of CO2 with propylene oxide and terpolymerization with aliphatic epoxides by bifunctional cobalt Salen complex

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