Size-dependent reactivity of Rh cationic clusters to reduce NO by CO in the gas phase at high temperatures

Author:

Miyajima Ken1ORCID,Nagata Toshiaki1ORCID,Mafuné Fumitaka1ORCID,Ichino Tomoya2ORCID,Maeda Satoshi23ORCID,Yoshinaga Taizo4,Miura Masahide4,Hayashi Takahiro4

Affiliation:

1. Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan

2. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, N21-W10, Kita-ku, Sapporo, Hokkaido 001-0021, Japan

3. Department of Chemistry, Faculty of Science, Hokkaido University, N10-W8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan

4. Advanced Material Engineering Division, Toyota Motor Corporation, 1200, Mishuku, Susono, Shizuoka 410-1193, Japan

Abstract

The reactivity of the reduction of NO pre-adsorbed on Rh2–9+ clusters by CO was investigated using an alternate on–off gas injection method, thermal desorption spectrometry, and quantum chemical calculations.

Publisher

Royal Society of Chemistry (RSC)

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