Selective thionation of naphtho[2,3-b]thiophene diimide: tuning of the optoelectronic properties and packing structure

Author:

Chen Wangqiao12345,Nakano Masahiro1234,Takimiya Kazuo1234ORCID,Zhang Qichun5678

Affiliation:

1. Emergent Molecular Function Research Group

2. RIKEN Center for Emergent Matter Science (CEMS)

3. Wako

4. Japan

5. School of Materials Science and Engineering

6. Nanyang Technological University

7. Singapore 639798

8. Singapore

Abstract

Naphtho[2,3-b]thiophene diimide was selectively thionated to afford the corresponding dicarboxy-dithiocarboxy diimide with a low-lying LUMO of −4.2 eV.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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