H2 addition to (Me4PCP)Ir(CO): studies of the isomerization mechanism-Reference-Cited by-同舟云学术

H2 addition to (Me4PCP)Ir(CO): studies of the isomerization mechanism

Published:2018 Issue:45 Volume:47 Page:16119-16125
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lekich Travis T.¹²³⁴,Gary J. Brannon⁵⁶⁷⁴,Bellows Sarina M.¹⁸⁹¹⁰⁴,Cundari Thomas R.¹⁸⁹¹⁰⁴^ORCID,Guard Louise M.¹²³⁴^ORCID,Heinekey D. Michael¹⁸⁹¹⁰⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Washington

3. Seattle

4. USA

5. Department of Chemistry & Biochemistry

6. Stephen F. Austin State University

7. Nacogdoches

8. Center for Advanced Scientific Computing and Modeling (CASCaM)

9. University of North Texas

10. Denton

Abstract

Compared to analogous sterically demanding complexes, the methyl derived pincer iridium complex shows enhanced reactivity with H₂ including: rapid isomerization from a cis- to trans-dihydride complex and solvent activation during isomerization.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02861C

Reference29 articles.

1. Acceptor PCP Pincer Iridium(I) Chemistry: Stabilization of Nonmeridional PCP Coordination Geometries

2. Dimerization of Alkynes Promoted by a Pincer-Ligated Iridium Complex. C−C Reductive Elimination Inhibited by Steric Crowding

3. Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes