A molecular sponge that exclusively adsorbs acetonitrile

Author:

Habata Yoichi12ORCID,Wada Ayumi1,Lee Eunji3ORCID,Ju Huieyong4ORCID,Yoshiba Yuki1,Horita Hiroki1ORCID,Ishii Jun-ichi12,Ikeda Mari5ORCID,Kuwahara Shunsuke12ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan

2. Research Center for Materials with Integrated Properties, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan

3. Department of Chemistry, Gangneung-Wonju National University, Gangneung 25457, South Korea

4. Western Seoul Center, Korea Basic Science Institute, 150 Bugahyeon-ro, Seodaemun-gu, Seoul 03759, South Korea

5. Department of chemistry, Education Center, Faculty of Engineering, Chiba Institute of Technology, Shobazono, Narashino, Chiba 275-0023, Japan

Abstract

A tetra-armed cyclen (L) with phenylethynylmethyl groups as side-arms forms L·CH3CN inclusion crystals from acetonitrile–organic mixed solvents with high selectivity.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Marubun Research Promotion Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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