Square-planar and octahedral nickel complexes of an acylhydrazone ligand and the serendipitous isolation of a potential octahedral nickel acylhydrazone precursor

Author:

Carballo Rosa12ORCID,Lago Ana Belén13ORCID,Vázquez-Toirán María1,Estévez Laura4ORCID,Vázquez-López Ezequiel M.12ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultade de Química, Universidade de Vigo, 36310 Vigo, Spain

2. Metallosupramolecular Chemistry Group, Galicia Sur Health Research Institute (IIS Galicia Sur). SERGAS-UVIGO, Galicia, Spain

3. Laboratorio de Materiales para Análisis Químico (MAT4LL), Departamento de Química, Unidad Departamental de Química Inorgánica, Universidad de La Laguna (ULL), Tenerife, La Laguna, 38206, Spain

4. Departamento de Química Física, Facultade de Química, Universidade de Vigo, 36310 Vigo, Spain

Abstract

An investigation of the coordination chemistry of the ((E)-N′-(4-hydroxybenzylidene)-4-hydroxybenzohydrazide) Schiff-based ligand (HL) towards Ni(ii) acetate was performed using single crystal X-ray diffraction.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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