Acceleration of CO2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics-Reference-Cited by-同舟云学术

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Acceleration of CO2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics

Published:2018 Issue:32 Volume:9 Page:6629-6638
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Heimann Jessica E.¹²³⁴,Bernskoetter Wesley H.¹⁵⁶⁴^ORCID,Hazari Nilay¹²³⁴^ORCID,Mayer James M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Yale University

3. New Haven

4. USA

5. University of Missouri

6. Columbia

Abstract

Kinetic studies of CO₂ insertion into transition metal hydrides provide evidence about the nature of the rate-determining transition state.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02535E

Reference59 articles.

1. Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain

2. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

3. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

4. CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

5. Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry

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