A coordinatively unsaturated iridium complex with an unsymmetrical redox-active ligand: (spectro)electrochemical and reactivity studies-Reference-Cited by-同舟云学术

A coordinatively unsaturated iridium complex with an unsymmetrical redox-active ligand: (spectro)electrochemical and reactivity studies

Published:2019 Issue:37 Volume:48 Page:13931-13942
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sobottka Sebastian¹²³⁴⁵,van der Meer Margarethe Behr¹²³⁴⁵,Glais Estelle¹²³⁴⁵,Albold Uta¹²³⁴⁵,Suhr Simon¹²³⁴⁵,Su Cheng-Yong⁶⁷⁸⁹^ORCID,Sarkar Biprajit¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Chemie und Biochemie

2. Anorganische Chemie

3. Freie Universität Berlin

4. Berlin

5. Germany

6. School of Chemistry and Chemical Engineering

7. Sun Yat-Sen University

8. Guangzhou,510275

9. China

Abstract

Metal–ligand cooperativity can be used in iridium complexes with an unsymmetrically substituted redox-active diamidobenzene ligand for bond activation reactions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01597C

Reference103 articles.

1. A series of metal complexes with the non-innocent N,N′-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure

2. Complete Electron-Transfer Series of the [M-N4] Type

3. Analysis and Interpretation of Metal-Radical Coupling in a Series of Square Planar Nickel Complexes: Correlated Ab Initio and Density Functional Investigation of [Ni(LISQ)2] (LISQ=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-))