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A chelated borinium cation

Published:2024 Issue:24 Volume:53 Page:10075-10078
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Major Christopher¹^ORCID,Lough Alan¹,Stephan Douglas W.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Toronto, 80 St George St, Toronto, ON, M5S3H6, Canada

2. Institute of Drug Discovery Technology, Ningbo University, Ningbo, Zhejiang, China

Abstract

Abstraction of fluoride from [RNSiMe2CH2]2BF (R = Dipp, 1-Ad) (Dipp = C6H3(iPr)2, Ad = C10H15) provides the corresponding chelated borinium salts, [(RNSiMe2CH2)2B][B(C6F5)4].

Funder

Natural Sciences and Engineering Research Council of Canada

University of Toronto

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01242A

Reference28 articles.

1. Borinium, Borenium, and Boronium Ions: Synthesis, Reactivity, and Applications

2. Gaseous bivalent boron cations: stability and structure

3. Dicoordinated boron cations dehydrate organic ethers in the gas phase

4. Gas-Phase Reactions of Dicoordinated Boron Cations with Alcohols

5. Synthesis of B, N, O-containing heterocycles via reaction of an aminoborinium ion with cyclic acetals and ketals

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1. Correction: A chelated borinium cation;Dalton Transactions;2024

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