Type-I dyotropic rearrangement for 1,2-disubstituted cyclohexanes: substitution effect on activation energy-Reference-Cited by-同舟云学术

Type-I dyotropic rearrangement for 1,2-disubstituted cyclohexanes: substitution effect on activation energy

Published:2016 Issue:13 Volume:6 Page:10549-10556
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Sheikh Nadeem S.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. King Faisal University

4. Al-Ahsa 31982

5. Saudi Arabia

Abstract

Migratory aptitude and contribution of specific structural features of synthetically valuable functional groups and halogen atoms in type-I dyotropic rearrangement for both symmetric and unsymmetrical 1,2-disubstituted cyclohexanes are computed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA25482E

Reference111 articles.

1. Dyotropic Rearrangements, a New Class of Orbital-Symmetry Controlled Reactions. Type I

2. The activation strain model and molecular orbital theory: understanding and designing chemical reactions

3. Reaction mechanisms: pericyclic reactions

4. Analogies between Synthetic and Biosynthetic Reactions in Which [1,2]-Alkyl Shifts Are Combined with Other Events: Dyotropic, Schmidt, and Carbocation Rearrangements

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