Induction of smectic polymorphism in bent-core derivatives of the 6-oxoverdazyl by partial fluorination of alkyl chains

Author:

Ciastek Sylwia1234,Kaszyński Piotr12345,Pociecha Damian6784,Jasiński Marcin1234

Affiliation:

1. Faculty of Chemistry

2. University of Łódź

3. 91-403 Łódź

4. Poland

5. Organic Materials Research Group

6. Department of Chemistry

7. University of Warsaw

8. 02-089 Warsaw

Abstract

A series of bent-core mesogens 2[m,n] derived from the 6-oxoverdazyl radical and containing partially fluorinated alkyl tails was prepared and investigated by thermal, optical, XRD and EPR methods.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference17 articles.

1. R. Tamura , Y.Uchida and K.Suzuki, in Handbook of Liquid Crystals, J. W. Goodby, P. J. Collings, T. Kato, C. Tschierske, H. F. Gleeson and P. Raynes, ed. Wiley-VCH, Weinheim, 2014, vol. 8, pp. 837–864

2. Positive Magneto-LC Effect in Conjugated Spin-Bearing Hexabenzocoronene

3. Stable radicals: fundamentals and applied aspects of odd-electron compounds, ed. R. G. Hicks, John Wiley & Sons, Chichester, 2010

4. Induction of Columnar Discotic Behavior in Verdazyl Radicals with Alkylsulfanyl Substituents

5. Thermochromic discotic 6-oxoverdazyls

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