Stepwise on-surface synthesis of thiophene-based polymeric ribbons by coupling reactions and the carbon–fluorine bond cleavage-Reference-Cited by-同舟云学术

Stepwise on-surface synthesis of thiophene-based polymeric ribbons by coupling reactions and the carbon–fluorine bond cleavage

Published:2022 Issue:2 Volume:24 Page:697-703
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liu Liqian¹,Zou Hengqi¹,Miao Xinrui¹^ORCID,Yip Hin-Lap¹²^ORCID,Deng Wenli¹^ORCID,Cao Yong¹

Affiliation:

1. Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China

2. Innovation Center of Printed Photovoltaics, South China Institute of Collaborative Innovation, Dongguan 523808, P. R. China

Abstract

STM results by stepwise annealing reveal the synthesis of surface-assisted polymeric ribbon involving C−Br, C−H and C−F dissociation by a combination of Ullmann, dehydrogenative, and cyclodehydrogenative coupling.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04039A

Reference41 articles.

1. Polythiophene derivatives compatible with both fullerene and non-fullerene acceptors for polymer solar cells

2. Synthesis of Conjugated Polymers for Organic Solar Cell Applications