Enhanced thermal stability of Cu–silylphosphido complexes via NHC ligation
Author:
Affiliation:
1. Department of Chemistry
2. The University of Western Ontario
3. London
4. N6A 5B7 Canada
5. Centre for Advanced Materials and Biomaterials Research
Abstract
The thermal stability of the Cu–P(SiMe3)2 moiety can be enhanced via N-heterocyclic carbene ligation.
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Foundation for Innovation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02040A
Reference39 articles.
1. Comparing the properties of homologous phosphido and amido complexes: synthesis and characterization of the disilylphosphido complexes {M[P(SiMe3)2]2}2 where M = zinc, cadmium, mercury, tin, lead and manganese
2. Synthesis of homoleptic silylphosphido complexes (M[P(SiMe3)2][.mu.-P(SiMe3)2])2, where M = zinc and cadmium, and their use in metalloorganic routes to Cd3P2 and MGeP2
3. Sol-gel-like route to crystalline cadmium phosphide nanoclusters
4. Silylphosphanes: Developments in Phosphorus Chemistry
5. Low-temperature organometallic synthesis of crystalline and glassy ternary semiconductors MIIMIVP2 where MII Zn and Cd, and MIV Ge and Sn
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