Rhodium-catalyzed sequential intermolecular hydroacylation and deconjugative isomerization toward diversified diketones-Reference-Cited by-同舟云学术

Rhodium-catalyzed sequential intermolecular hydroacylation and deconjugative isomerization toward diversified diketones

Published:2021 Issue:1 Volume:8 Page:39-45
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

You Guirong¹²³⁴⁵,Chang Zhi-Xin⁵⁶⁷⁸⁴,Yan Jizhong¹²³⁴,Xia Chengcai⁵⁶⁷⁸⁴^ORCID,Li Fu-Rong⁵⁶⁷⁸⁴,Li Hong-Shuang⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. College of Pharmaceutical Science

2. Zhejiang University of Technology

3. Hangzhou 310014

4. China

5. Institute of Pharmacology

6. School of Pharmaceutical Sciences

7. Shandong First Medical University & Shandong Academy of Medical Sciences

8. Taian 271016

Abstract

A rhodium(i)-catalyzed reaction via an intermolecular hydroacylation/deconjugative isomerization cascade was developed which enabled the facile synthesis of valuable 1,4-, 1,5-, and 1,6-diketones with good to excellent yields.

Funder

Natural Science Foundation of Shandong Province

Key Technology Research and Development Program of Shandong

Shandong First Medical University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01174F

Reference53 articles.

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4. Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch

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