Donor–acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy

Author:

Chaudhari Sachin R.12345,Griffin John M.67896ORCID,Broch Katharina101112139,Lesage Anne12345,Lemaur Vincent1415161718,Dudenko Dmytro1415161718,Olivier Yoann1415161718ORCID,Sirringhaus Henning101112139,Emsley Lyndon19202122,Grey Clare P.612239

Affiliation:

1. Institut des Sciences Analytiques

2. Centre de RMN à Très Hauts Champs

3. Université de Lyon (CNRS/ENS Lyon/UCB Lyon 1)

4. 69100 Villeurbanne

5. France

6. Department of Chemistry

7. Lancaster University

8. Lancaster LA1 4YB

9. UK

10. Optoelectronics Group

11. Cavendish Laboratory

12. University of Cambridge

13. Cambridge CB3 0HE

14. Laboratory for Chemistry of Novel Materials

15. Center for Innovation and Research in Materials and Polymers (CIRMAP)

16. Université de Mons (UMons)

17. 7000 Mons

18. Belgium

19. Institut des Sciences et Ingénierie Chimiques

20. Ecole Polytechnique Fédérale de Lausanne (EPFL)

21. CH-1015 Lausanne

22. Switzerland

23. Cambridge CB2 1EW

Abstract

DPP-DTT adopts a donor-on-acceptor stacking arrangement which is preserved in thin films.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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