An effective strategy for creating asymmetric MOFs for chirality induction: a chiral Zr-based MOF for enantioselective epoxidation

Abstract

A simple and rapid procedure was used to prepare chiral NU-1000 as a robust Zr-based MOF without complexity. The functionalization of NU-1000 was performed by utilizing chirall-(+)-tartaric acidviasolvent-assisted linker incorporation, resulting in [C-NU-1000]. A Mo-complex was immobilized onto chiral NU-1000 for enantioselective epoxidation.