Palladium aminopyridine complexes catalyzed selective benzylic C–H oxidations with peracetic acid-Reference-Cited by-同舟云学术

Palladium aminopyridine complexes catalyzed selective benzylic C–H oxidations with peracetic acid

Published:2020 Issue:32 Volume:49 Page:11150-11156
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lubov Dmitry P.¹²³⁴²,Lyakin Oleg Yu.¹²³⁴²,Samsonenko Denis G.⁴²³⁵²^ORCID,Rybalova Tatyana V.⁴²³⁶²,Talsi Evgenii P.¹²³⁴²^ORCID,Bryliakov Konstantin P.¹²³⁴²^ORCID

Affiliation:

1. Boreskov Institute of Catalysis

2. Novosibirsk 630090

3. Russia

4. Novosibirsk State University

5. Nikolaev Institute of Inorganic Chemistry

6. Vorozhtsov Novosibirsk Institute of Organic Chemistry

Abstract

Palladium complexes with tripodal ligands of the tpa family efficiently catalyze benzylic C–H oxidation of various substrates with peracetic acid, affording the corresponding ketones in high yields (up to 100%), at <1 mol% catalyst loadings.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02247K

Reference71 articles.

1. Evolution of C–H Bond Functionalization from Methane to Methodology

2. Aliphatic C–H Oxidations for Late-Stage Functionalization

3. An overview of late-stage functionalization in today’s drug discovery