Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(iii) complex I: synthesis, spectroscopy and static quantum chemistry-Reference-Cited by-同舟云学术

Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(iii) complex I: synthesis, spectroscopy and static quantum chemistry

Published:2021 Issue:32 Volume:12 Page:10780-10790
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dorn Matthias¹,Kalmbach Jens²,Boden Pit³,Kruse Ayla⁴,Dab Chahinez⁵^ORCID,Reber Christian⁵^ORCID,Niedner-Schatteburg Gereon³^ORCID,Lochbrunner Stefan⁴^ORCID,Gerhards Markus³^ORCID,Seitz Michael²^ORCID,Heinze Katja¹^ORCID

Affiliation:

1. Department of Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10-14, 55128 Mainz, Germany

2. Institute of Inorganic Chemistry, University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

3. Department of Chemistry and Research Center Optimas, Technical University Kaiserslautern, Erwin-Schrödinger-Straße, 67663 Kaiserslautern, Germany

4. Institute for Physics, Department of Life, Light and Matter, University of Rostock, 18051 Rostock, Germany

5. Département de chimie, Université de Montréal, Montréal, Québec, H3C 3J7, Canada

Abstract

Vanadium is an abundant and cheap metal but near-infrared luminescent vanadium complexes are extremely rare with largely unexplored photophysics and photochemistry. We delineate the photodynamics of VCl3(ddpd) to infer novel design strategies.

Funder

Deutsche Forschungsgemeinschaft

Natural Sciences and Engineering Research Council of Canada

Fonds de recherche du Québec – Nature et technologies

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02137K

Reference97 articles.

1. Luminescent Ionic Transition-Metal Complexes for Light-Emitting Electrochemical Cells