Reversible transformation between Cu(i)-thiophenolate coordination polymers displaying luminescence and electrical properties

Author:

Troyano Javier1234,Castillo Óscar15674,Amo-Ochoa Pilar12348ORCID,Martínez J. Ignacio91034ORCID,Zamora Félix12348ORCID,Delgado Salomé12348

Affiliation:

1. Departamento de Química Inorgánica

2. Universidad Autónoma de Madrid

3. 28049 Madrid

4. Spain

5. Universidad del País Vasco

6. UPV/EHU

7. E-48080 Bilbao

8. Institute for Advanced Research in Chemical Sciences (IAdChem)

9. Departamento de Nanoestructuras, Superficies, Recubrimientos y Astrofísica Molecular

10. Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC)

Abstract

The direct self-assembly between CuI with thiophenol produces two different 1D coordination polymers (CPs) with multifunctional properties; the ratio CuI in acetonitrile is the key factor determining the reversible conversion between both CPs.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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