Monohalogenated carbamates where hydrogen bonding rules without halogen bonding: is there a link between poor carbamate crystal growth and Z′

Monohalogenated carbamates where hydrogen bonding rules without halogen bonding: is there a link between poor carbamate crystal growth and Z′ > 1?

Published:2019 Issue:27 Volume:21 Page:4048-4062
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Mocilac Pavle¹²³⁴^ORCID,Gallagher John F.¹²³⁴^ORCID

Affiliation:

1. School of Chemical Sciences

2. Dublin City University

3. Dublin 9

4. Ireland

Abstract

Monohalogenated carbamates (CxxX) aggregate by N–H⋯N interactions without halogen bonding and crystallise as poor quality crystalline fibres often with Z′ > 1.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE00318E

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