Synthesis of a diboryl-N-heterocycle and its conversion to a bidentate cationic Lewis acid

Author:

Farrell Jeffrey M.1234,Stephan Douglas W.1234

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

Abstract

Sequential reaction of 2-lithio-1-methylimidazole with 9-borabicyclo[3.3.1]nonane (9-BBN) dimer and 9-Cl-9-BBN yields diboryl-N-heterocycle C4H5N2(H)(BC8H14)2 (1).

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Structural Variations of FLPs;A Primer in Frustrated Lewis Pair Hydrogenation: Concepts to Applications;2021-11-17

2. FLP reactivity of [Ph3C]+ and (o-tolyl)3P and the capture of a Staudinger reaction intermediate;Dalton Transactions;2017

3. Cyclic Dinuclear Organotin Cations Stabilized by Bulky Substituents;Organometallics;2015-11-19

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