Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases
Author:
Affiliation:
1. Department of Chemical and Materials Engineering
2. New Mexico State University
3. Las Cruces
4. USA
5. Materials Physics & Applications Division
6. Center for Integrated Nanotechnologies
7. Los Alamos National Laboratory
Abstract
The polymerization rate decreases in the nanoconfined structure compared to the bulk state due to the segregation effect, which increases the local monomer concentration and enhances the termination reaction.
Funder
National Science Foundation
Bureau of Reclamation
Basic Energy Sciences
U.S. Department of the Interior
Los Alamos National Laboratory
National Nuclear Security Administration
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SM/C9SM01565E
Reference76 articles.
1. Nanostructure Evolution during Photopolymerization in Lyotropic Liquid Crystal Templates
2. Photopolymerization Kinetics and Structure Development of Templated Lyotropic Liquid Crystalline Systems
3. Polymerization of the Inverted Hexagonal Phase
4. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
5. A new family of mesoporous molecular sieves prepared with liquid crystal templates
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