The influence of bicarbonate concentration and ionic strength on peroxide speciation and overall reactivity towards UO<sub>2</sub>-Reference-Cited by-同舟云学术

The influence of bicarbonate concentration and ionic strength on peroxide speciation and overall reactivity towards UO₂

Published:2024 Issue:23 Volume:14 Page:16248-16254
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Olsson Daniel¹^ORCID,Aydogan Hazal¹,Jonsson Mats¹^ORCID

Affiliation:

1. Department of Chemistry, KTH Royal Institute of Technology, Stockholm, SE-100 44, Sweden

Abstract

Coordination of H2O2 by UO22+ suppresses reaction between H2O2 and UO2 in bicarbonate solutions. The suppression is greater at lower [CO32−] due to higher fractions of (UO2)x(O2)y(CO3)z2x−2y−2z.

Funder

Svensk Kärnbränslehantering

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA02281E

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Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Effect of hydrogen on oxidative dissolution of epsilon particles-doped UO2 pellets under carbonate condition with hydrogen peroxide;Journal of Nuclear Materials;2025-01

2. Correction: The influence of bicarbonate concentration and ionic strength on peroxide speciation and overall reactivity towards UO₂;RSC Advances;2024