Assignment of photoelectron spectra of intramolecular silicon complexes: 1-vinyl- and 1-phenylsilatranes

Author:

Belogolova Elena F.1234ORCID,Doronina Evgeniya P.1234ORCID,Sidorkin Valery F.1234ORCID

Affiliation:

1. A. E. Favorsky Irkutsk Institute of Chemistry

2. Siberian Branch of the Russian Academy of Sciences Favorsky

3. Irkutsk 664033

4. Russian Federation

Abstract

The problematic photoelectron spectra of 1-vinyl- and 1-phenylsilatranes were theoretically studied and the correlation between the VIE and thedSiNwas proposed to be used for the identification of orbitals in the Si←N coordination bond in XSi[OCH2CH2]3N.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference76 articles.

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3. V. Pestunovich , S.Kirpichenko and M.Voronkov , in The Chemistry of Organic Silicon Compounds , ed. Z. Rappoport and Y. Apeloig , Wiley , Chichester, UK , 1998 , ch. 24, vol. 2, pp. 1447–1537

4. Silatrane-based surface chemistry for immobilization of DNA, protein-DNA complexes and other biological materials

5. M. G. Voronkov and V. P.Baryshok , in Use of Silatranes for Medicine and Agriculture , ed. G. A. Tolstikov , Publishing House of the Siberian Branch of Russian Academy of Sciences , Novosibirsk , 2005 , p. 258

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1. Computational liquid-phase and solid-state 29Si NMR;Russian Chemical Reviews;2020-04-01

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