Visible light mediated oxidation of benzylic sp3 C–H bonds using catalytic 1,4-hydroquinone, or its biorenewable glucoside, arbutin, as a pre-oxidant

Author:

Finney Laura C.12345ORCID,Mitchell Lorna J.12345,Moody Christopher J.12345ORCID

Affiliation:

1. School of Chemistry

2. University of Nottingham

3. University Park

4. Nottingham

5. UK

Abstract

Benzylic ethers undergo a visible light induced C–H activation and oxygen insertion to give the corresponding benzoate esters in moderate to good yields.

Funder

Engineering and Physical Sciences Research Council

University of Nottingham

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference77 articles.

1. A. H. Haines , Methods for Oxidation of Organic Compounds. Alkanes, Alkenes, Alkynes and Arenes , Academic Press , London , 1985

2. A. H. Haines , Methods for Oxidation of Organic Compounds. Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds, Hydroxyarenes and Aminoarenes , Academic Press , London , 1988

3. Modern Oxidation Methods , ed. J. E. Bäckvall , Wiley-VCH , Weinheim , 2nd edn, 2010

4. P. L. Fuchs , Handbook of Reagents for Organic Synthesis: Catalytic Oxidation Reagents , John Wiley & Sons Ltd , 2013

5. The Applications of Dimethyl Sulfoxide as Reagent in Organic Synthesis

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