A new suprasterol by photochemical reaction of 1α,25-dihydroxy-9-methylene-19-norvitamin D3

Author:

Kulesza Urszula12345,Plum Lori A.6789,DeLuca Hector F.6789,Mouriño Antonio510111213ORCID,Sicinski Rafal R.1234

Affiliation:

1. Faculty of Chemistry

2. University of Warsaw

3. 02-093 Warsaw

4. Poland

5. Departamento de Química Orgánica

6. Department of Biochemistry

7. University of Wisconsin-Madison

8. Madison

9. USA

10. Laboratorio de Investigación Ignacio Ribas

11. Universidad de Santiago de Compostela

12. 15782 Santiago de Compostela

13. Spain

Abstract

The structure of the product of the UV-induced photochemical reaction of 1α,25-dihydroxy-9-methylene-19-norvitamin D3 has been established and the possible reaction paths are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference27 articles.

1. Z. Rappoport , The chemistry of dienes and polyenes, in The chemistry of functional groups, ed. Z. Rappoport, An Interscience Publication, John Wiley & Sons, Ltd, 1997 and 2000, vol. 1 and 2

2. Vitamin D: A millenium perspective

3. T. C. Chen , Z.Lu and M. F.Holick, Photobiology of vitamin D, in Vitamin D: Physiology, molecular biology and clinical applications, ed. M. F. Holick, Humana Press, 2010

4. M. F. Holick , Photobiology of vitamin D, in Vitamin D, ed. D. Feldman, J. W. Pike and J. S. Adams, Elsevier Academic Press, 3rd edn, 2011

5. Photochemistry of Vitamin D and its Isomers and of Simple Trienes

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