Aryl sulfonyl fluoride synthesisviapalladium-catalyzed fluorosulfonylation of aryl thianthrenium salts

Author:

Shan Lingling1,Ma Zhanhu1,Ou Caiyun1,Cai Yinxia1,Ma Yuyang1,Guo Yong2ORCID,Ma Xiaoyu1ORCID,Liu Chao12ORCID

Affiliation:

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, China

2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

Abstract

A palladium-catalyzed fluorosulfonylation reaction of aryl thianthrenium salts was developed to efficiently produce diverse aryl sulfonyl fluorides in moderate to good yieldsviaa radical sulfur dioxide insertion and fluorination strategy.

Funder

Science and Technology Commission of Shanghai Municipality

Shanghai Institute of Technology

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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