The synthesis, molecular structure and interconversion of two novel benzene-coordinated pentaruthenium–carbido cluster isomers [Ru5C(CO)12(µ3: η2: η2: η2-C6H6)] and [Ru5C(CO)12(η6-C6H6)]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1992/C3/C39920000177
Reference10 articles.
1. The chemistry of polynuclear compounds. Part XXVI. Products of the pyrolysis of dodecacarbonyl-triangulo-triruthenium and -triosmium
2. Benzene in a new face-capping bonding mode: molecular structures of [Ru6C(CO)11(µ3-η2: η2:η2-C6H6)(η6-C6H6)] and [Os3(CO)9(µ3-η2: η2:η2-C6H6)]
3. The synthesis of [Ru5C(CO)15] by the carbonylation of [Ru6C(CO)17] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru5C(CO)15], [Ru5C(CO)15(MeCN)], [Ru5C(CO)14(PPh3)], [Ru5C(CO)13(PPh3)2], and [Ru5(µ-H)2C(CO)12{Ph2P(CH2)2PPh2}]
4. Synthesis and characterisation of [Ru3(CO)9(µ3-η2:η2:η2-C6H6)]
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